1394134-51-0

Basic information

• Product Name: N-(2-bromo-4,5-dimethoxybenzyl)-4-methoxy-N-methylaniline
• Synonyms: N-(2-bromo-4,5-dimethoxybenzyl)-4-methoxy-N-methylaniline
• CAS NO: 1394134-51-0
• Molecular Weight: 366.255
• Mol File: 1394134-51-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2-bromo-4,5-dimethoxybenzyl)-4-methoxy-N-methylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-bromo-4,5-dimethoxybenzyl)-4-methoxy-N-methylaniline(1394134-51-0)
• EPA Substance Registry System: N-(2-bromo-4,5-dimethoxybenzyl)-4-methoxy-N-methylaniline(1394134-51-0)

Safety Data

• Hazardous Substances Data: 1394134-51-0(Hazardous Substances Data)

Upstream product

• 54370-00-2 2-bromo-4,5-dimethoxybenzyl alcohol 

Relevant articles and documents

Intramolecular direct dehydrohalide coupling promoted by KOtBu: Total synthesis of amaryllidaceae alkaloids anhydrolycorinone and oxoassoanine

A transition-metal-free intramolecular dehydrohalide coupling via intramolecular homolytic aromatic substitution (HAS) with aryl radicals has been developed in the presence of potassium tert-butoxide and an organic molecule as the catalyst. The methodology has been applied to a concise synthesis of Amaryllidaceae alkaloids viz. oxoassoanine (1b), anhydrolycorinone (1d), and other related structures. Interestingly, the method also works only in the presence of potassium tert-butoxide.