1394135-62-6

Basic information

• Product Name: 4-methyl-1-(2-(phenylsulfonyl)ethyl)-2,6,7-trioxabicyclo[2.2.2]octane
• Synonyms: 4-methyl-1-(2-(phenylsulfonyl)ethyl)-2,6,7-trioxabicyclo[2.2.2]octane
• CAS NO: 1394135-62-6
• Molecular Weight: 298.36
• Mol File: 1394135-62-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-methyl-1-(2-(phenylsulfonyl)ethyl)-2,6,7-trioxabicyclo[2.2.2]octane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-1-(2-(phenylsulfonyl)ethyl)-2,6,7-trioxabicyclo[2.2.2]octane(1394135-62-6)
• EPA Substance Registry System: 4-methyl-1-(2-(phenylsulfonyl)ethyl)-2,6,7-trioxabicyclo[2.2.2]octane(1394135-62-6)

Safety Data

• Hazardous Substances Data: 1394135-62-6(Hazardous Substances Data)

Upstream product

• 1394135-60-4 (3-methyloxetan-3-yl)methyl3-(phenylsulfonyl)propanoate 
• 10154-71-9 3-(phenylsulfonyl)propionic acid 
• 873-55-2 sodium benzenesulfonate 

Relevant articles and documents

4-methyl-1-(2-(phenylsulfonyl)ethyl)-2,6,7-trioxabicyclo[2.2.2]octane

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Synthesis of 6,6′-binaphthopyran-2-one natural products: Pigmentosin A, talaroderxines A and B

Efficient and stereoselective syntheses of pigmentosin A, talaroderxine A, and its diastereomer talaroderxine B are reported. The binaphthyl ring system is assembled by vanadium-catalyzed phenolic coupling of tricyclic precursors. These key intermediates were prepared by Michael-Dieckmann annulation of a protected orsellinate ester, with the requisite pyranones accessed by a new variant of Ghosez's sulfone-epoxide annulation. Preliminary biological experiments are reported for pigmentosin.