Cas 1394252-80-2,(2S,3S,4a'R,6'S,8a'S)-2',2'-di-tert-butyl-6'-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(diisopropoxy(methyl)silyl)tetrahydro-4'H-spiro[oxirane-2,7'-pyrano[3,2-d][1,3,2]dioxasiline]

1394252-80-2

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Basic information

Product Name: (2S,3S,4a'R,6'S,8a'S)-2',2'-di-tert-butyl-6'-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(diisopropoxy(methyl)silyl)tetrahydro-4'H-spiro[oxirane-2,7'-pyrano[3,2-d][1,3,2]dioxasiline]
Synonyms: (2S,3S,4a'R,6'S,8a'S)-2',2'-di-tert-butyl-6'-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(diisopropoxy(methyl)silyl)tetrahydro-4'H-spiro[oxirane-2,7'-pyrano[3,2-d][1,3,2]dioxasiline]
CAS NO:1394252-80-2
Molecular Formula:
Molecular Weight: 729.189
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (2S,3S,4a'R,6'S,8a'S)-2',2'-di-tert-butyl-6'-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(diisopropoxy(methyl)silyl)tetrahydro-4'H-spiro[oxirane-2,7'-pyrano[3,2-d][1,3,2]dioxasiline](CAS DataBase Reference)
NIST Chemistry Reference: (2S,3S,4a'R,6'S,8a'S)-2',2'-di-tert-butyl-6'-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(diisopropoxy(methyl)silyl)tetrahydro-4'H-spiro[oxirane-2,7'-pyrano[3,2-d][1,3,2]dioxasiline](1394252-80-2)
EPA Substance Registry System: (2S,3S,4a'R,6'S,8a'S)-2',2'-di-tert-butyl-6'-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(diisopropoxy(methyl)silyl)tetrahydro-4'H-spiro[oxirane-2,7'-pyrano[3,2-d][1,3,2]dioxasiline](1394252-80-2)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 1394252-80-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 1394252-80-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,9,4,2,5 and 2 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1394252-80:
(9*1)+(8*3)+(7*9)+(6*4)+(5*2)+(4*5)+(3*2)+(2*8)+(1*0)=172
172 % 10 = 2
So 1394252-80-2 is a valid CAS Registry Number.

1394252-80-2Upstream product

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1394252-80-2Relevant academic research and scientific papers

Mechanism of the regio- and diastereoselective ring expansion reaction using trimethylsilyldiazomethane

Sakai, Takeo,Ito, Satoshi,Furuta, Hiroki,Kawahara, Yuki,Mori, Yuji

supporting information, p. 4564 - 4567 (2012/11/07)

An equatorial attack of TMS-diazomethane was determined to be the first step of the BF3-promoted ring expansion reaction of six-membered ketones using TMS-diazomethane. The migration reaction occurred in a conformation in which the carbonyl oxygen and the TMS group were antiperiplanar to predominantly afford trans-seven-membered ketones.

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