Cas 139426-72-5,Rh((C6H2(OCH3)3)3P)2(CNC(CH3)3)2(2+)*2B(C6H5)4(1-)={Rh((C6H2(OCH3)3)3P)2(CNC(CH3)3)2}{B(C6H5)4}2

139426-72-5

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Basic information

Product Name: Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2⁽²⁺⁾*2B(C₆H₅)4^(1-)={Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2}{B(C₆H₅)4}2
Synonyms:
CAS NO:139426-72-5
Molecular Formula:
Molecular Weight: 1972.69
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2⁽²⁺⁾*2B(C₆H₅)4^(1-)={Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2}{B(C₆H₅)4}2(CAS DataBase Reference)
NIST Chemistry Reference: Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2⁽²⁺⁾*2B(C₆H₅)4^(1-)={Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2}{B(C₆H₅)4}2(139426-72-5)
EPA Substance Registry System: Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2⁽²⁺⁾*2B(C₆H₅)4^(1-)={Rh((C₆H₂(OCH₃)3)3P)2(CNC(CH₃)3)2}{B(C₆H₅)4}2(139426-72-5)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 139426-72-5(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 139426-72-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,9,4,2 and 6 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 139426-72:
(8*1)+(7*3)+(6*9)+(5*4)+(4*2)+(3*6)+(2*7)+(1*2)=145
145 % 10 = 5
So 139426-72-5 is a valid CAS Registry Number.

139426-72-5Upstream product

119072-55-8 tert-butylisonitrile

139426-72-5Downstream Products

139426-72-5Relevant academic research and scientific papers

Structural and spectroscopic characterization of a paramagnetic isocyanide complex of rhodium(II)

Dunbar, Kim R.,Haefner, Steven C.

, p. 1431 - 1433 (1992)

The remarkably stable paramagnetic Rh(II) complex [Rh(η3-TMPP)2][BF4]2 (TMPP = tris(2,4,6-trimethoxyphenyl)phosphine) reacts with 2 equiv of tert-butyl isocyanide to yield the air-stable mononuctear Rh(II) complex [Rh(η3-TMPP)2(CNBut)2][BF 4]2. A single-crystal X-ray diffraction study reveals that the cation adopts a distorted-square-planar geometry in which the phosphine ligands are trans rather than cis as in the parent complex. The paramagnetism of this unusual four-coordinate Rh(II) metallo radical was probed by a variety of spectroscopic and magnetic techniques.

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