139495-48-0Relevant academic research and scientific papers
Addition of Stannylenes to Iminoboranes
Paetzold, Peter,Hahnfeld, Detlef,Englert, Ulli
, p. 1079 - 1082 (2007/10/02)
Iminoboranes tBuBNR (R = tBu, Mes: 1a, b) undergo aminostannation by the diaminostannylene Sn2 (2b) to give (Me3Si)2N-B(tBu)=NR-Sn-N(SiMe3)2 (4a, b).The stannylene 4b remains monomeric in the crystal (space group P21/n).The cyclic diaminostannylene (3b), instead, simply adds the boranes 1a, b across one of its Sn-N bonds to form the bicyclohexene-type products 5a, b.Key Words: Iminoboranes / Stannylenes / Aminostannation
