139499-79-9Relevant academic research and scientific papers
BISDIENOPHILES IN THE DIELS-ALDER REACTION. V. KINETICS AND THERMOCHEMISTRY OF THE REACTION OF N,N'-BISDICHLOROMALEIMIDES WITH 1,3-DIPHENYLISOBENZOFURAN
Adigezalov, N. R.,Kiselev, V. D.,Konovalov, A. I.
, p. 1558 - 1562 (2007/10/02)
A series of N,N'-bisdichloromaleimides, which are potential bisdienophiles in the production of high-molecular polyadducts in the Diels-Alder reaction with bisdienes, were synthesized.The rate constants and activation parameters, determined for the first stage in the formation of the monoadduct, and the enthalpy of the reaction with 1,3-diphenylisobenzofuran show that the synthesis of polyadducts based on N,N'-bisdichloromaleimides, which are potential fire-proofing agents, is associated with unfavorable kinetic and thermodynamic characteristics.
