1395342-32-1Relevant academic research and scientific papers
Iridium-catalyzed allylation of chiral β-stereogenic alcohols: Bypassing discrete formation of epimerizable aldehydes
Schmitt, Daniel C.,Dechert-Schmitt, Anne-Marie R.,Krische, Michael J.
supporting information, p. 6302 - 6305 (2013/02/25)
The cyclometalated π-allyliridium 3,4-dinitro-C,O-benzoate complex modified by (R)- or (S)-Cl,MeO-BIPHEP promotes the transfer hydrogenative coupling of allyl acetate to β-stereogenic alcohols with good to excellent levels of catalyst-directed diastereose
A modular, stereoselective approach to spiroketal synthesis
Crimmins, Michael T.,Azman, Adam M.
supporting information; experimental part, p. 1489 - 1492 (2012/08/08)
A highly convergent and flexible synthetic approach to stereochemically defined spiroketals is reported. Substituents can be incorporated at various positions around the spiroketal framework without significant disruption to the synthetic scheme. The approach has been exploited to prepare the spiroketal fragment of milbemycin β Georg Thieme Verlag Stuttgart · New York.
