139535-05-0

Upstream product

• 501-53-1 benzyl chloroformate 

Downstream Products

• 81102-13-8 benzyl 4-(N-benzyloxycarbonyl-D-alanylamino)-2-(benzyloxycarbonyl)amino-2,3,4-trideoxy-β-DL-threo-pentopyranoside 
• 139588-65-1 benzyl 4-(N-benzyloxycarbonyl-D-alanylamino)-2-(benzyloxycarbonyl)amino-2,3,4-trideoxy-α-DL-threo-pentopyranoside 
• 81102-12-7 ((2S,3S,5S)-5-Amino-2-benzyloxy-tetrahydro-pyran-3-yl)-carbamic acid benzyl ester 
• 81102-12-7 benzyl 4-amino-2-(benzyloxycarbonyl)amino-2,3,4-trideoxy-β-DL-threo-pentopyranoside 

Relevant academic research and scientific papers

Total synthesis of 4-(D-alanylamino)-2-amino-2,3,4-trideoxy-DL-threo-pentose (3-deoxy-DL-prumycin)

3-Deoxy-DL-prumycin (1) was synthesized from 2-furanmethanol (2-furfuryl alcohol, 2) in eleven steps in 15% total yield. Michael addition of azide anion to 2,3-dideoxy-DL-pent-2-enopyranos-4-ulose (3) and reduction in situ of the adduct afforded the key i