139560-99-9Relevant academic research and scientific papers
Dehydroamino acid derivatives from D-arabinose and L-serine: Synthesis of models for the azinomycin antitumor antibiotics
Moran,Tellew,Zhao,Armstrong
, p. 7848 - 7859 (2007/10/02)
Synthesis of aldehydes 17 from D-arabinose and 31 from L-serine provided key precursors for the generation of highly functionalized dehydroamino acid derivatives upon condensation with glycyl phosphonates. Subsequent bromination and intramolecular additio
Stereoselective Synthesis of (E)- and (Z)-1-Azabicyclohex-2-ylidene Dehydroamino Acid Derivatives
Armstrong, Robert W.,Tellew, John E.,Moran, Edmund J.
, p. 2208 - 2211 (2007/10/02)
Bromination of dehydroamino acid derivatives with NBS or Br2/2,6-lutidine yields (E)- or (Z)-β-bromodehydroamino acid derivatives selectively.Subsequent intramolecular Michael addition-elimination of an aziridine proceeds with complete retention of olefin
