13960-01-5Relevant academic research and scientific papers
Comparison of ullmann/RCM and ullmann/bis-hydrazone coupling reactions; New access to benzodithiophenes for dye-sensitized solar cell and thiahelicene applications
Stephenson, G. Richard,Cauteruccio, Silvia,Doulcet, Julien
, p. 701 - 707 (2014/04/03)
The use of CuTC (Liebeskind's catalyst), followed by methylenation and ring-closing metathesis, or bis-hydrazone coupling reactions is described. This approach establishes an alternative non-photochemical synthesis of the strategically important 1,2-b:4,3-b′ BDT regioisomer, which has previously been underused in applications such as dye-sensitized solar cells and nonlinear optics because of the difficulty of synthesis on a large scale. Georg Thieme Verlag Stuttgart. New York.
Novel synthesis of arylboronic acids by electroreduction of aromatic halides in the presence of trialkyl borates
Laza, Carine,Dunach, Elisabet,Serein-Spirau, Francoise,Moreau, Joel J. E.,Vellutini, Luc
, p. 373 - 375 (2007/10/03)
A novel preparation of aryl and heteroarylboronic acids by an electrochemical coupling reaction is described. It is based on the reductive coupling between aromatic or heteroaromatic halides and a trialkyl borate. The reactions are carried out in DMF or THF with the use of sacrificial aluminium or magnesium anodes in a single-compartment cell. Arylboronic acids are obtained with moderate to good selectivities and isolated yields.
