139615-69-3

Basic information

• Product Name: (2-Methyl-6-nitro-hept-2-ene-4-sulfonyl)-benzene
• CAS NO: 139615-69-3
• Molecular Weight: 297.375
• Mol File: 139615-69-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-Methyl-6-nitro-hept-2-ene-4-sulfonyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Methyl-6-nitro-hept-2-ene-4-sulfonyl)-benzene(139615-69-3)
• EPA Substance Registry System: (2-Methyl-6-nitro-hept-2-ene-4-sulfonyl)-benzene(139615-69-3)

Safety Data

• Hazardous Substances Data: 139615-69-3(Hazardous Substances Data)

Upstream product

• 79-24-3 Nitroethane 
• 102860-20-8 4-Methyl-2-(phenylsulfonyl)-1,3-pentadiene 

Downstream Products

• 16647-04-4 6-methyl-3,5-heptadien-2-one 
• 62692-45-9 4-Benzenesulfonyl-6-methyl-hept-5-en-2-one 

Relevant articles and documents

Stereoselective synthesis of (3E,5E)-dien-2-ones and (2E,4E)-dienals via 2-phenylsulfonyl 1,3-dienes

Michael addition of nitroalkanes to 2-phenylsulfonyl 1,3 dienes proceeded smoothly in the presence of DBU to give nitrosulfones (e.g. 2) in high yield. Transformation of the nitro group of the adduct to a keto function (Nef type reaction) and subsequent elimination of benzenesulfinic acid afforded conjugated dienones and dienals with high stereoselectivity.