139615-76-2

Basic information

• Product Name: Benzene, [(1-methylene-2-octenyl)sulfonyl]-, (E)-
• CAS NO: 139615-76-2
• Molecular Formula: C15H20O2S
• Molecular Weight: 264.389
• Mol File: 139615-76-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methylene-2-octenyl)sulfonyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methylene-2-octenyl)sulfonyl]-, (E)-(139615-76-2)
• EPA Substance Registry System: Benzene, [(1-methylene-2-octenyl)sulfonyl]-, (E)-(139615-76-2)

Safety Data

• Hazardous Substances Data: 139615-76-2(Hazardous Substances Data)

Upstream product

• 60805-71-2 phenylselenyl benzenesulfonate 
• 77192-27-9 (E)-1,3-nonadiene 

Downstream Products

• 25152-84-5 trans,trans-2,4-decadienal 
• 134005-54-2 methyl 3-(phenylsulfonyl)-4(E)-decenoate 
• 18836-52-7 (2E,4E)-N-isobutyldecadienamide 
• 7328-33-8 methyl (2E,4E)-decadienoate 
• 134005-51-9 (E)-3-Benzenesulfonyl-dec-4-enenitrile 
• 139615-74-0 ((E)-1-Nitro-dec-4-ene-3-sulfonyl)-benzene 
• 139615-72-8 ((E)-2-Nitro-undec-5-ene-4-sulfonyl)-benzene 

Relevant articles and documents

Synthesis of 2(E),4(E)-Dienamides and 2(E),4(E)-Dienoates from 1,3-Dienes via 2-Phenylsulfonyl 1,3-Dienes

A procedure for the preparation of 2E,4E unsaturated carboxylic acid derivatives from dienes was developed.Transformation of terminal 1,3-dienes to (E)-2-phenylsulfonyl 1,3-dienes and subsequent addition of a carboxy anion equivalent and elimination of benzenesulfinic acid led to 2,4-dienoic amides and esters.In this way the natural products N-isobutyl-2(E),4(E)-undecadienamide (1a), N-isobutyl-2(E),4(E)-decadienamide (pellitorine, 1b), and methyl 2(E),4(E)-decadienoate (1c) were obtained in high isomeric purity.