139620-40-9

Basic information

• Product Name: Pyridine, 2-(4-pentenylthio)-
• CAS NO: 139620-40-9
• Molecular Formula: C10H13NS
• Molecular Weight: 179.286
• Mol File: 139620-40-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-(4-pentenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-(4-pentenylthio)-(139620-40-9)
• EPA Substance Registry System: Pyridine, 2-(4-pentenylthio)-(139620-40-9)

Safety Data

• Hazardous Substances Data: 139620-40-9(Hazardous Substances Data)

Upstream product

• 197148-70-2 hex-5-enoic acid 2-thioxo-2H-pyridin-1-yl ester 
• 79-35-6 1,1'-dichloro-2,2'-difluoroethene 

Relevant articles and documents

Cyclization of Hindered Fluorinated Dichloro(5- And 6-)alkenyl Radicals. Structural Effects of Olefins on the Selective Formation of 5-exo and 6-endo Cyclization Products

Reaction of 3-butenyl radicals generated by photolysis of variously substituted Barton esters (both open-chain 1a-d and cyclohexyl 1e-h) with CF2=CCl2 gave a mixture of cyclized products (cyclopentanes 6 and 8 and cyclohexanes 7 and 9) as well as noncyclized products (4 and 5) in various ratios depending on the substitution pattern at the olefinic moiety. The product ratios of [cyclization (6 + 7 + 8 + 9):noncyclization (5)] for 1 with more alkyl substituents on the CC double bond were greater than those for 1 with fewer substituents. The products ratio of [5-exo (6 + 8): 6-endo (7 + 9)] was influenced by a steric effect. Photoreaction of Barton ester 2 with CF2=CCl2 gave a mixture of cyclohexanes 16 and 17 as well as noncyclized 14 and 15. Dehydrochlorination of decalins 7g and 7h followed by oxidation of sulfide and [2,3]sigmatropic rearrangement of the allyl sulfoxide gave octahydronaphthalenones 23 and 27, respectively.