13964-92-6

Upstream product

• 53433-12-8 [bis(triphenylphospine)nitrogen⁽¹⁺⁾][Co(CO)4] 
• 14878-26-3 potassium tetracarbonylcobaltate 

Downstream Products

• 38855-43-5 α-(2,4-Xylidin-1-yl)benzyl-phenylketon 
• 80783-93-3 N-(2,4-Dimethyl-phenyl)-N-(2-oxo-1,2-diphenyl-ethyl)-acetamide 
• 80783-95-5 2-(2,6-Dimethyl-phenylamino)-1,2-diphenyl-ethanone 
• 80783-94-4 N-(2,6-Dimethyl-phenyl)-N-(2-oxo-1,2-diphenyl-ethyl)-acetamide 
• 5722-91-8 1,2-diphenyl-2-(phenylamino)ethanone 
• 5326-56-7 N-(α'-oxo-bibenzyl-α-yl)-acetanilide 
• 80783-92-2 N-(2-Oxo-1,2-diphenyl-ethyl)-N-phenyl-propionamide 
• 19339-72-1 2-((4-methoxyphenyl)amino)-1,2-diphenylethan-1-one 
• 80783-91-1 N-(4-Methoxy-phenyl)-N-(2-oxo-1,2-diphenyl-ethyl)-acetamide 

Relevant academic research and scientific papers

PREPARATION AND PROPERTIES OF ACETYLIODOTRICARBONYLCOBALTATE; A NOVEL PRODUCT FROM THE REACTION OF METHYL IODIDE WITH TETRACARBONYLCOBALTATE

The reaction of PPN with an excess of methyl iodide in THF at 0 deg C gives almost quantitatively PPNI>, which has been shown by X-ray crystallography and spectroscopic measurements to adopt a trigonal bipyramidal structure with three carbonyls in the equatorial plane; it reacts with hydrogen or with sulfuric acid to give acetaldehyde, and with methanol/pyridine to give methyl acetate.The new anion is of interest as a potential intermediate in the cobalt/iodine catalyzed carbonylation or hydrocarbonylation of methanol.