139670-58-9Relevant academic research and scientific papers
Synthesis of Nitriles from Aldehydes with Elongation of the Molecule with Two Carbon Atoms
Afanasyev, Oleg I.,Zarochintsev, Alexander,Petrushina, Tatiana,Cherkasova, Anastasia,Denisov, Gleb,Cherkashchenko, Ilia,Chusova, Olga,Jinho, Oh,Man-Seog, Chun,Usanov, Dmitry L.,Semenov, Sergei E.,Chusov, Denis
supporting information, p. 32 - 35 (2018/12/05)
A new protocol for the synthesis of nitriles from carbonyl compounds with elongation of the molecule with two carbon atoms was developed. It involves a reaction of ethyl cyanoacetate with different aldehydes in the presence of iron pentacarbonyl as a redu
Catalytic sp3C-CN Bond Cleavage: Ni-Mediated Phosphorylation of Alkylnitriles
Zhang, Ji-Shu,Chen, Tieqiao,Zhou, Yongbo,Yin, Shuang-Feng,Han, Li-Biao
, p. 6746 - 6749 (2018/10/25)
A direct phosphorylation of the sp3C-CN bond catalyzed by a nickel catalyst is disclosed. A wide range of primary nitriles readily coupled with secondary phosphine oxides to produce the corresponding phosphorylated products in high yields. As a key step, this new method was applied to the synthesis of anticancer drug Combretastatin-A4, significantly shortening its synthetic path.
The novel preparation of hydrocinnamonitriles via the reduction of α- phenylsulfonyl cinnamonitriles with SmI2/CH3OH/THF system
Guo, Hongyun,Zhang, Yongmin
, p. 1879 - 1885 (2007/10/03)
Hydrocinnamonitriles were readily obtained via the reduction of α- phenylsulfonyl cinnamonitriles by SmI2/CH3OH/THF system.
LONG-RANGE EXCITON COUPLING FROM DIPYRRINONE CHROMOPHORES
Byun, Young-Seok,Lightner, D. A.
, p. 9759 - 9772 (2007/10/02)
Dipyrrinone chromophores, attached by their acid termini to give (1R,2R)-cyclohexanediol dipropionate and diacetate esters (xanthobilirubinate and nor-xanthobilirubinate, respectively), interact through exciton coupling, as evidenced by intense bisignate
