1396797-91-3Relevant academic research and scientific papers
Dinuclear iron complex-catalyzed cross-coupling of primary alkyl fluorides with aryl grignard reagents
Mo, Zhenbo,Zhang, Qiang,Deng, Liang
, p. 6518 - 6521 (2012)
Iron-catalyzed cross-coupling of nonactivated primary alkyl fluorides with aryl Grignard reagents has been achieved by using the low-coordinate dinuclear iron complex [(IPr2Me2)Fe(μ2-NDipp) 2Fe(IPr2Me2)] as the catalyst. This iron-catalyzed C(sp3)-F bond arylation reaction is applicable to a variety of aryl Grignard reagents and primary alkyl fluorides. The product pattern suggests the involvement of a radical-type mechanism for its C-F bond scission step.
