139694-40-9

Upstream product

• 141271-37-6 (1R,2S,3R,4R)-3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1,5-dimethyl-bicyclo[2.2.2]oct-5-ene-2-carboxylic acid methyl ester 

Downstream Products

• 141210-95-9 (1S,2R,5R,6R)-5-Acetyl-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-2-vinyl-cyclohexanecarboxylic acid methyl ester 
• 139694-44-3 (1S,2R,5S)-2-Methyl-5-(2-methyl-[1,3]dioxolan-2-yl)-2-vinyl-cyclohexanecarboxylic acid 
• 139694-43-2 (1S,2R,5S)-2-Methyl-5-(2-methyl-[1,3]dioxolan-2-yl)-2-vinyl-cyclohexanecarboxylic acid methyl ester 
• 139694-42-1 (1S,2R,5S,6R)-5-Acetyl-6-formyl-2-methyl-2-vinyl-cyclohexanecarboxylic acid methyl ester 
• 139694-36-3 (1R,2S,3R,6S)-6-Acetyl-3-methyl-3-vinyl-cyclohexane-1,2-dicarboxylic acid 2-methyl ester 
• 141210-94-8 (1S,2R,5S)-5-[2-Benzenesulfonyl-1-methylene-3-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-propyl]-2-methyl-2-vinyl-cyclohexanecarboxylic acid methyl ester 
• 141210-98-2 (1S,2R,5S)-5-[2-Benzenesulfonyl-1-hydroxy-1-methyl-3-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-propyl]-2-methyl-2-vinyl-cyclohexanecarboxylic acid methyl ester 
• 141210-99-3 {(1S,2R,5S)-2-Methyl-5-[1-methylene-3-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-propyl]-2-vinyl-cyclohexyl}-methanol 
• 141211-01-0 (R)-5-[(E)-3-((1S,3R,4R)-3-Isopropenyl-4-methyl-4-vinyl-cyclohexyl)-but-2-enyl]-2,2,4,4-tetramethyl-[1,3]dioxolane 
• 141211-00-9 {(1S,2R,5S)-2-Methyl-5-[(E)-1-methyl-3-((R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-propenyl]-2-vinyl-cyclohexyl}-methanol 
• 71593-07-2 (1R,2R,4S,17R)-loba-8,10,13⁽¹⁵⁾-triene-17,18-diol 

Relevant academic research and scientific papers

Synthesis of (1R,2R,4S,17R)-loba-8,10-13(15)-triene-17,18-diol, a marine diterpene

Synthesis of marine diterpene 1 (1R,2R,4S,17R) has been achieved via coupling of ketone 7 and sulfone 6, leading to the determination of the absolute stereochemistry.

Total synthesis of marine diterpene fuscol

Marine diterpene fuscol was synthesized stereoselectively from D-mannitol via bicyclo[2.2.2]octane derivative 4, and its complete structure was established.