139705-14-9Relevant academic research and scientific papers
Monomer and Dimer 1,3-Diaza-2-phosphaallyllithium Complexes: Structures and Ambident Reactivity
Detsch, Ralph,Niecke, Edgar,Nieger, Martin,Schoeller, Wolfgang W.
, p. 1119 - 1124 (2007/10/02)
Metallation of the NH-functional amino(imino)phosphaes Mes*NPNHR (R = CPh3; Ad, tBu) 1a-c yields the 1,3-diaza-2-phosphaallyllithium compounds 2a-c.The crystal structure shows an ether-stabilized monomer of 2a and a solvent-free dimer with an eight-membered ring in the case of 2b, c.The reaction of 2b with chlorodiphenylphosphane yields, dependent on the reaction conditions, (phosphanylamino)iminophosphane 3 or bis(imino)phosphanylphosphorane 4.The structural and reactivity is discussed on the basis of ab initio calculations.Key Words: 1,3-Diaza-2-phosphaallyllithium / Calculations, ab initio
