139723-70-9

Upstream product

• 139723-69-6 tert-Butyl-[(Z)-(R)-1-((4S,5S)-5-ethynyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-diphenyl-silane 
• 41349-38-6 methyl 7-bromohept-5-ynoate 
• 31608-24-9 2-(7-Bromo-hept-5-ynyloxy)-tetrahydro-pyran 
• 82358-88-1 [(3aR,4R,6R,6aS)-6-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-acetic acid ethyl ester 
• 139740-60-6 (3aS,4R,6R,6aR)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-((Z)-oct-2-enyl)-tetrahydro-furo[3,4-d][1,3]dioxole 
• 139723-67-4 (3aR,4S,6R,6aR)-4-Chloromethyl-2,2-dimethyl-6-((Z)-oct-2-enyl)-tetrahydro-furo[3,4-d][1,3]dioxole 
• 139891-86-4 [(3aS,4R,6R,6aR)-2,2-Dimethyl-6-((Z)-oct-2-enyl)-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-methanol 
• 139723-68-5 (Z)-(R)-1-((4R,5S)-5-Ethynyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-non-3-en-1-ol 
• 4762-26-9 hexyltriphenylphosphonium bromide 
• 1720-37-2 2-(hex-5-yn-1-yloxy)tetrahydro-2H-pyran 

Downstream Products

• 119238-83-4 10(S),11(R),12(R)-Trihydroxyeicosa-5(Z),8(Z),14(Z)-Trienoic Acid 
• 139723-71-0 (5Z,8Z)-9-{(4S,5S)-5-[(Z)-(R)-1-(tert-Butyl-diphenyl-silanyloxy)-non-3-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-nona-5,8-dienoic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective Synthesis of 10(S),11(R),12(R)-Trihydroxyeicosa-5(Z),8(Z),14(Z)-Trienoic Acid from D-Mannose

A stereoselective synthesis of the title compound, from D-mannose using base induced double elimination of β-alkoxy chloride as key step is described.