1397293-68-3Relevant academic research and scientific papers
Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
K?nigs, C. David F.,Müller, Maria F.,Aiguabella, Nuria,Klare, Hendrik F. T.,Oestreich, Martin
, p. 1506 - 1508 (2013)
A base-free, catalytic protocol for the dehydrogenative Si-N coupling of weakly nucleophilic N-H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si-H bond activation at a Ru-S bond generates a silicon electrophile that forms a Si-N bond prior to the N-H deprotonation by an intermediate Ru-H complex, only releasing H 2. The Royal Society of Chemistry 2013.
Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes
Itagaki, Shintaro,Kamata, Keigo,Yamaguchi, Kazuya,Mizuno, Noritaka
supporting information; experimental part, p. 9269 - 9271 (2012/09/22)
In the presence of Rh2(OAc)4 (OAc = acetate) and TBA2WO4 (TBA = tetra-n-butylammonium), the N-silylation of indole derivatives with hydrosilanes efficiently proceeded to give the corresponding N-silylated indole
