139732-86-8Relevant articles and documents
REACTIONS OF CYCLOPOLYPHOSPHINES WITH ZEROVALENT PLATINUM GROUP METAL COMPLEXES
Cavell, Ronald G.,Phillips, Ian G.
, p. 117 - 120 (2007/10/02)
Perfluoromethyldiphosphene complexes are ultimately formed from the reactions of (CF3P)4,5 with low valent Pt group metals.Evidence for oxidative addition to Pt(0) and Pd(0) to form intermediate complexes is found.The heterocyclic ligand oxidatively adds to Pt(0) to form a metallocycle.The five membered ring coordinates to Pt(0) via the olefinic group.