139747-87-8

Basic information

• Product Name: Pentanedioic acid, 3-phenyl-, mono(1-methylethyl) ester (9CI)
• Synonyms: Pentanedioic acid, 3-phenyl-, mono(1-methylethyl) ester (9CI);Pentanedioic acid, 3-phenyl-, Mono(1-Methylethyl) ester
• CAS NO: 139747-87-8
• Molecular Formula: C14H18O4
• Molecular Weight: 250.29032
• Product Categories: ACIDHALIDE
• Mol File: 139747-87-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Pentanedioic acid, 3-phenyl-, mono(1-methylethyl) ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Pentanedioic acid, 3-phenyl-, mono(1-methylethyl) ester (9CI)(139747-87-8)
• EPA Substance Registry System: Pentanedioic acid, 3-phenyl-, mono(1-methylethyl) ester (9CI)(139747-87-8)

Safety Data

• Hazardous Substances Data: 139747-87-8(Hazardous Substances Data)

Upstream product

• 4160-80-9 3-phenylglutaric acid anhydride 
• 67-63-0 isopropyl alcohol 

Relevant articles and documents

N-Heterocyclic carbene as a Br?nsted base catalyst for the amination of naphthol derivatives and alcoholysis of glutaric anhydrides

A non-covalent Br?nsted-basic N-heterocyclic carbene catalyzed (NHC) Friedel-Crafts type amination of naphthol derivatives using dialkyl azodicarboxylates as the aminating source and alcoholysis of various glutaric anhydrides using alcohol as pronucleophile is presented. Both of these reactions are performed in the presence of either commercially available free-carbene catalyst or in situ-generated carbene catalyst. Friedel-Crafts type amination reaction is an example of a hydroxy group facilitated amination reaction. Both reactions proceed via in situ activations of –OH group by the carbene catalyst through hydrogen bonding interaction and furnish the relevant products in moderate to excellent yields.