139759-74-3Relevant academic research and scientific papers
Enol Cation Radicals in Solution. 4. An Improved Synthesis of 4,6,7-Trimethylbenzofurans by Oxidation of β-Mesityl Substituted Enols
Roeck, Maik,Schmittel, Michael
, p. 325 - 329 (1994)
An improved synthetic access for the construction of 4,6,7-trimethylbenzofurans (B1-B8) through the one-electron oxidation of mesityl-substituted enols (E1-E8) is presented.The transformation can be accomplished in good to excellent yields by using variou
Reaction of Enol Cation Radicals in the Presence of Nucleophiles
Schmittel, Michael,Roeck, Maik
, p. 1611 - 1620 (2007/10/02)
The one-electron oxidation chemistry of three diaryl-substituted enols, 1,1-dimesityl-1-propen-2-ol (7), 1,2-dimesityl-1-propen-1-ol (8), and 2-mesityl-2-phenylethenol (9), has been examined.As a consequence of the pronounced steric shielding around the β
