139766-37-3

Upstream product

• 3112-85-4 methylphenylsulfonate 
• 167959-48-0 1-phenyl-3-(phenylsulfonyl)-propan-1-ol 
• 139766-01-1 1-(tert-butyldimethylsilyloxy)-1-phenyl-3-(phenylsulfonyl)propane 
• 139766-11-3 5-(tert-butyldimethylsilyloxy)-5-phenyl-3-phenylsulfonyl-2-pentanol 2-benzoate 
• 96-09-3 styrene oxide 
• 254761-89-2 (Z)-1-phenyl-3-phenylsulfonyl-3-penten-1-ol 
• 139766-22-6 (E)-1-phenyl-3-phenylsulfonyl-3-penten-1-ol 

Relevant academic research and scientific papers

Stereoselective Synthesis of 2,5-Dialkyl-3-(phenylsulfonyl) Tetrahydrofurans via Cyclisation of Z-Sulfonyl-substituted Homoallylic Alcohols

Z-Sulfonyl-substituted homoallylic alcohols 3 underwent highly anti-selective base-mediated 5-endo-trig cyclisation reactions to give 2,5-dialkyl-3-phenylsulfonyl tetrahydrofurans anti-2.A simple steric model is proposed to account for the high selectivit

Stereoselective synthesis of 3-(phenylsulphonyl)-2,5 disubstituted tetrahydrofurans via 5-endo-trig ring-closure reactions

The synthesis and stereoselective 5-endo-trig cyclization reactions of a series of sulphonyl-substituted homoallylic alcohols are reported. Some competing reactions are described, and a model is proposed to account for the observed stereoselectivity.