1398567-31-1

Upstream product

• 79887-09-5 (4-butylphenyl)acetylene 

Downstream Products

• 1398567-33-3 3-(4-butylphenyl)-4-iodo-1-methoxy-1H-pyrano[4,3-b]quinoline 
• 1398566-86-3 3-(4-butylphenyl)-1-methoxy-4-((4-methoxyphenyl)-ethynyl)-1H-pyrano[4,3-b]quinoline 
• 1398566-87-4 3-(4-butylphenyl)-1-methoxy-4-(thiophen-3-ylethynyl)-1H-pyrano[4,3-b]quinoline 
• 1398567-18-4 3-(4-butylphenyl)-1-methoxy-4-(phenylethynyl)-1H-pyrano[4,3-b]quinoline 
• 1398567-06-0 3-(4-butylbenzoyl)-1-(4-methoxyphenyl)pyrrolo[1,2-a]quinoline-4-carbaldehyde 
• 1398567-07-1 3-(4-butylbenzoyl)-1-(thiophen-3-yl)pyrrolo[1,2-a]quinoline-4-carbaldehyde 
• 1398567-25-3 3-(4-butylbenzoyl)-2-iodo-1-phenylpyrrolo[1,2-a]quinoline-4-carbaldehyde 
• 1398567-26-4 3-(4-butylbenzoyl)-2-iodo-1-(thiophen-3-yl)pyrrolo[1,2-a]quinoline-4-carbaldehyde 

Relevant academic research and scientific papers

Tandem 6π-Azatriene Electrocyclization of Fused Amino-cyclopentenones: Synthesis of Functionalized Pyrrolo- And Indolo-quinoxalines

A tandem 6π-azacyclization approach for the synthesis of diversified pyrrolo/indolo[1,2-a]quinoxalines from amino-cyclopentenones has been developed. The reaction proceeds through a trifluoroacetic-acid-mediated 6π-electrocyclization and concomitant opening of the cyclopentenone ring. The advantageous features of the developed chemistry include transition-metal-free conditions, operational simplicity, and a broad substrate scope. Further X-ray crystallographic studies confirm the assigned structures of the fused heterocycles.