139885-10-2Relevant academic research and scientific papers
TANDEM ALKYNE INSERTION AND ALLYL SULFONIUM YLIDE REARRANGEMENT OF γ,δ-ALKYNYL-α'-DIAZOKETONES
Hoye, Thomas R.,Dinsmore, Christopher J.
, p. 169 - 172 (2007/10/02)
Acetylenic α-diazaketones 1, when treated with catalytic rhodium carboxylate dimer and diallylsulfide (1.1 equiv), undergo sequential alkyne insertion/ylide formation/sigmatropic rearrangements to give γ-allylthio cyclic enones.This transformation was use
