139914-54-8Relevant articles and documents
Homoconjugation and transannular orbital interactions detected by photoelectron and13C-NMR spectroscopy. Bicyclo[3.3.1]nona-3,7-diene-2,6-dione and bicyclo[3.3.1]nonane-2,6-dione
Doerner, Thomas,Gleiter, Rolf,Robbins, Timothy A.,Chayangkoon, Paochai,Lightner, David A.
, p. 3235 - 3241 (2007/10/02)
Transannular orbital interactions between two ketone carbonyl groups located at positions 2 and 6 on the bicyclo[3.3.1]nonane carbocyclic framework were detected by 13C-NMR and photoelectron spectroscopy (PES). Thus, an ~4.4-ppm shielding of th