139932-91-5Relevant academic research and scientific papers
Regioselective Synthesis of the Kinamycin ABCD ring system
O'Sullivan, Patrick J.,Moreno, Rafael,Murphy, William S.
, p. 535 - 538 (2007/10/02)
The new bromoquinone-enamine annulation was successfully extended to acyclic enamino ketones resulting in a new synthesis of the ABC framework 7 of kinamycins and when applied to cyclic enamino ketones 8a-c the first synthesis of their ABCD ring system.Smooth aromatisation of compounds 4b,d to 9a,b respectively was effected with DDQ. - Key Words: regiospecific annulation, metal catalysed; kinamycin; tetrahydrobenzocarbazole
