1399320-41-2Relevant academic research and scientific papers
Metal- and chemical-oxidant-free c-h/c-h cross-coupling of aromatic compounds: The use of radical-cation pools
Morofuji, Tatsuya,Shimizu, Akihiro,Yoshida, Jun-Ichi
supporting information; experimental part, p. 7259 - 7262 (2012/09/07)
Pool and couple: A method for oxidative C-H/C-H cross-coupling has been developed using "radical-cation pools". Aromatic compounds react with aryl radical cations, which are generated and accumulated by low-temperature electrolysis (see scheme). This method avoids both the nonselective oxidation of substrates and oxidation of products and effects the C-H/C-H cross-coupling of aromatic compounds without metal complexes and chemical oxidants. Copyright
