139940-58-2Relevant academic research and scientific papers
Organometallic chemistry of diphosphazanes IV. Reactions of the cyclodiphosphazane, cis-tBuNP(OPh)>2 with M(CO)6 (M = Cr, Mo, W), rhodium(I), palladium(II) and platinum(II) derivatives
Balakrishna, M.S.,Krishnamurthy, S.S.
, p. 243 - 251 (1992)
The reactions of the cyclodiphosphazane, cis-tBuNP(OPh)>2(L) with M(CO)6 (M = Cr, Mo or W) as well as PdII and PtII derivatives afford mononuclear complexes of the type (M = Cr, Mo or W) and (M = Pt or Pd) in which the cyclodiphosphazane acts as a monodentate ligand.Reactions with RhI derivatives yield the complexes (COD = 1.5-cyclooctadiene) and 2 in which the cyclodiphosphazane exhibits monodentate and bridged-bidentate modes of coordination, respectively.The structures of the complexes have been deduced mainly from 31P NMR spectroscopic data.
