139958-93-3Relevant articles and documents
Synthesis of some mellein derivatives
Bhide, B H,Akolkar, V D,Brahmbhatt, D I
, p. 116 - 117 (2007/10/02)
Synthesis of some mellein derivatives (IIIa-d) have been carried out using o-lithiation reaction. o-Lithiation of substituted N-methylbenzamides (Ia-d) and with n-BuLi followed by alkylation with propylene oxide gives 3-methyl-3,4-dihydroisocoumarins (IIa-c) and 5,6-dimethoxymellein (IIId). (IIa-c) have been converted to IIIa-c by HBr/AcOH or anhyd.AlCl3.