139975-59-0Relevant academic research and scientific papers
A Difference CD Method for Determining Absolute Stereochemistry of Acyclic 1,2,4-Triols
Mori, Yuji,Furukawa, Hiroshi
, p. 6725 - 6738 (2007/10/02)
A general method based on difference circular dichroic (DIF CD) spectroscopy for assigning the absolute configuration of 1,2,4-triol is presented.Four possible stereoisomers of 6-heptene-1,2,4-triol were prepared and served as models to develop the procedure.The sign of the DIF CD Cotton effect is correlated to the absolute configuration of the C2 position.
