14003-53-3Relevant academic research and scientific papers
Electrophilic reactions of fluorocarbons under the action of aluminum chlorofluoride, a potent Lewis acid
Petrov, V. A.,Krespan, C. G.,Smart, B. E.
, p. 138 - 142 (2007/10/03)
A new Lewis acid - aluminum chlorofluoride - was demonstrated to be an effective catalyst for the isomerisation of fluoroolefins, polyfluorinated epoxides and cyclopropanes.At ambient temperature this catalyst converts perfluorobutadiene-1,3 into perfluorobutyne-2 and perfluoro(4-methylpentene-2) into perfluoro(2-methylpentene-2) in nearly quantitative yield.At 100 deg C, aluminum chlorofluoride causes the cleavage of perfluorinated tertiary amines. - Keywords: Electrophilic reactions; Fluorocarbons; Aluminum chlorofluoride; Lewis acid; NMR spectroscopy
