14004-17-2Relevant academic research and scientific papers
Regio- and stereoselective copper-induced isomerization of 2-alkenyl 2-lithiophenyl ethers to 2-(2-alkenyl)phenols
Barluenga, Jose,Sanz, Roberto,Fananas, Francisco J.
, p. 6103 - 6106 (2007/10/03)
N-Allyl-N-(2-lithioallyl)aniline undergoes intramolecular carbometallation via 5-exo addition on treatment with CuCN. 2-Alkenyl 2-bromophenyl ethers rearrange to 2-(2-alkenyl)phenols by bromine-lithium exchange and further transmetallation with CuCN.
A short and efficient synthesis of grisan
Kaufman,Sindelar
, p. 879 - 881 (2007/10/02)
A three-step synthesis of grisan (spiro[benzofuran-2(3H)-1'-cyclohexane]), using methoxymethoxybenzene and 1-chloromethylcyclohexane as starting materials, is described.
