1400880-85-4Relevant academic research and scientific papers
The importance of hydrogen bonding to stereoselectivity and catalyst turnover in gold-catalyzed cyclization of monoallylic diols
Ghebreghiorgis, Thomas,Biannic, Berenger,Aponick, Aaron,Kirk, Brian H.,Ess, Daniel H.
supporting information, p. 16307 - 16318,12 (2020/09/09)
Density functional calculations and experiment were used to examine the mechanism, reactivity, and origin of chirality transfer in monophosphine Au-catalyzed monoallylic diol cyclization reactions. The lowest energy pathway for cyclization involves a two-
