14009-71-3Relevant articles and documents
Vanadium(V)-catalyzed oxidation of (3R)-linalool - The selective formation of furanoid linalool oxides and their conversion into isocyclocapitelline derivatives
Hartung, Jens,Drees, Simone,Geiss, Barbara,Schmidt, Philipp
, p. 223 - 226 (2007/10/03)
Oxidation of (3R)-linalool (2) with tert-butyl hydroperoxide (TBHP) occurs at the 6,7-position to selectively afford linalool oxide cis-1, if catalyzed by vanadium(V) Schiff base complexes 4. Substituted tetrahydrofuran cis-1 and its isomer trans-1 served
The Use of Acyclic Monoterpenes in the Preparation of β-pyrones; Synthesis of the Right-hand Fragment of Usneoidone E
Urones, Julio G.,Diez, David,Marcos, Isidro S.,Basabe, Pilar,Lithgow, Anna M.,et al.
, p. 3691 - 3704 (2007/10/02)
The right hand fragment, 36, of Usneoidone E, 1, a powerful antiviral and antitumoural agent has been synthesized from the β-pyrone 32.Using lanalool as starting material, a 2,2,6,6-tetrasubstituted dihydropyrane 20, precursor of 32 and 33, was prepared. 20 was also synthesized from geranyl acetate through selenide 7, and is a versatile precursor for the synthesis of tetraprenyltoluquinols.Unambiguous 13C NMR assignment has been done by 2D correlations.
