1400993-72-7Relevant academic research and scientific papers
Catalytic Radical Process for Enantioselective Amination of C(sp3)?H Bonds
Li, Chaoqun,Lang, Kai,Lu, Hongjian,Hu, Yang,Cui, Xin,Wojtas, Lukasz,Zhang, X. Peter
supporting information, p. 16837 - 16841 (2018/11/23)
A new catalytic radical system involving CoII-based metalloradical catalysis is effective in activating sulfamoyl azides for enantioselective radical 1,6-amination of C(sp3)?H bonds, affording six-membered chiral heterocyclic sulfami
Stereoselective radical amination of electron-deficient C(sp3)-H bonds by Co(II)-based metalloradical catalysis: Direct synthesis of α-amino acid derivatives via α-C-H amination
Lu, Hongjian,Hu, Yang,Jiang, Huiling,Wojtas, Lukasz,Zhang, X. Peter
supporting information, p. 5158 - 5161,4 (2012/12/12)
The cobalt(II) complex of 3,5-DitBu-IbuPhyrin, [Co(P1)], is an effective catalyst for intramolecular amination of electron-deficient C-H bonds, including those adjacent to electron-withdrawing CO2R, C(O)NR 2, C(O)R, and CN groups, in excellent yields with high regio- and stereoselectivity. The [Co(P1)]-catalyzed amination system provides a direct method for the synthesis of α-amino acid derivatives from the corresponding carboxylate precursors.
Stereoselective radical amination of electron-deficient C(sp3)-H bonds by Co(II)-based metalloradical catalysis: Direct synthesis of α-amino acid derivatives via α-C-H amination
Lu, Hongjian,Hu, Yang,Jiang, Huiling,Wojtas, Lukasz,Zhang, X. Peter
supporting information, p. 5158 - 5161 (2013/01/15)
The cobalt(II) complex of 3,5-DitBu-IbuPhyrin, [Co(P1)], is an effective catalyst for intramolecular amination of electron-deficient C-H bonds, including those adjacent to electron-withdrawing CO2R, C(O)NR 2, C(O)R, and CN groups, in excellent yields with high regio- and stereoselectivity. The [Co(P1)]-catalyzed amination system provides a direct method for the synthesis of α-amino acid derivatives from the corresponding carboxylate precursors.
