1401032-81-2Relevant academic research and scientific papers
Activation of hydrogen and hydrogenation catalysis by a borenium cation
Farrell, Jeffrey M.,Hatnean, Jillian A.,Stephan, Douglas W.
supporting information, p. 15728 - 15731,4 (2020/08/24)
The readily prepared borenium salt [(IiPr2)(BC8H 14)][B(C6F5)4] (2) [IiPr2 = C3H2(NiPr)2] is shown to activate H 2 heterolytically in the presence of tBu3P. Compound 2 also acts as a catalyst for the metal-free hydrogenation of imines and enamines at room temperature.
