140137-16-2Relevant academic research and scientific papers
A Convenient One-pot Synthesis of α-Fluoro-α,β-unsaturated Nitriles From Diethyl Cyanofluoromethanephosphonate
Xu, Ze-Qi,DesMarteau, Darryl D.
, p. 313 - 316 (2007/10/02)
The carbanion of diethyl 1-cyano-1-fluoromethanephosphonate 3, generated in situ from diethyl cyanomethanephosphonate 2 and N-fluorobis(trifluoromethanesulfonyl)imide 1, undergoes the Wittig-Horner reaction with aldehydes and ketones to yield α-fluoro-α,β-unsaturated nitriles 5.
