140137-77-5Relevant articles and documents
Pd-catalyzed couplings of (α-fluoro)vinyl tris(trimethylsilyl) germanes
Wang, Zhizhong,Gonzalez, Aurelio,Wnuk, Stanislaw F.
, p. 5313 - 5316 (2005)
The (α-fluoro)vinyl tris(trimethylsilyl)germanes undergo Pd-catalyzed cross-couplings with aryl and alkenyl halides upon oxidative treatment with hydrogen peroxide under basic aqueous conditions to give access to fluoroalkenes and fluorodienes with retent
Nucleophilic Desulfinylation of α-Fluoro-β-(alkoxy and silyloxy) Sulfoxides. Effects of the β-Oxy Substituent on Protonation, 1,2-Hydrogen Migration, and Nucleophile Addition to the Fluorocarbenoid Centers
Uno, Hidemitsu,Sakamoto, Katsuji,Suzuki, Hitomi
, p. 218 - 227 (2007/10/02)
Treatment of 2-(4-biphenylyl)-2-t-butyldimethylsilyloxy-1-chloro-1-fluoroethyl phenyl sulfoxide with PhMgBr resulted in the formation of a fluorostilbene derivative, a fluoro enol silyl ether and small amounts of 4-(fluoroacetyl)biphenyl, while a similar