140137-77-5

Basic information

• Product Name: Benzene, 1,1'-(1-fluoro-1-butene-1,4-diyl)bis-, (Z)-
• CAS NO: 140137-77-5
• Molecular Formula: C16H15F
• Molecular Weight: 226.294
• Mol File: 140137-77-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-fluoro-1-butene-1,4-diyl)bis-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-fluoro-1-butene-1,4-diyl)bis-, (Z)-(140137-77-5)
• EPA Substance Registry System: Benzene, 1,1'-(1-fluoro-1-butene-1,4-diyl)bis-, (Z)-(140137-77-5)

Safety Data

• Hazardous Substances Data: 140137-77-5(Hazardous Substances Data)

Upstream product

• 140137-82-2 1-chloro-1-fluoro-2-methoxymethoxy-4-phenylbutyl phenyl sulfoxide 
• 140137-84-4 2-(t-butyldimethylsilyloxy)-1-chloro-1-fluoro-4-phenylbutyl phenyl sulfoxide 
• 591-50-4 iodobenzene 
• 108-86-1 bromobenzene 
• 260262-16-6 (Z,E)-1-Chloro-1-fluoro-2-phenethylethene 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

Pd-catalyzed couplings of (α-fluoro)vinyl tris(trimethylsilyl) germanes

The (α-fluoro)vinyl tris(trimethylsilyl)germanes undergo Pd-catalyzed cross-couplings with aryl and alkenyl halides upon oxidative treatment with hydrogen peroxide under basic aqueous conditions to give access to fluoroalkenes and fluorodienes with retent

Nucleophilic Desulfinylation of α-Fluoro-β-(alkoxy and silyloxy) Sulfoxides. Effects of the β-Oxy Substituent on Protonation, 1,2-Hydrogen Migration, and Nucleophile Addition to the Fluorocarbenoid Centers

Treatment of 2-(4-biphenylyl)-2-t-butyldimethylsilyloxy-1-chloro-1-fluoroethyl phenyl sulfoxide with PhMgBr resulted in the formation of a fluorostilbene derivative, a fluoro enol silyl ether and small amounts of 4-(fluoroacetyl)biphenyl, while a similar