140138-39-2

Basic information

• Product Name: (-)-(3S,4R,5R)-3-(3',4'5'-trimethoxybenzyl)-4-(3'',4''-methylenedioxybenzyl)-5-(1-menthyloxy)butyrolactone
• Synonyms: (-)-(3S,4R,5R)-3-(3',4'5'-trimethoxybenzyl)-4-(3'',4''-methylenedioxybenzyl)-5-(1-menthyloxy)butyrolactone
• CAS NO: 140138-39-2
• Molecular Weight: 554.681
• Mol File: 140138-39-2.mol

Chemical Properties

• CAS DataBase Reference: (-)-(3S,4R,5R)-3-(3',4'5'-trimethoxybenzyl)-4-(3'',4''-methylenedioxybenzyl)-5-(1-menthyloxy)butyrolactone(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(3S,4R,5R)-3-(3',4'5'-trimethoxybenzyl)-4-(3'',4''-methylenedioxybenzyl)-5-(1-menthyloxy)butyrolactone(140138-39-2)
• EPA Substance Registry System: (-)-(3S,4R,5R)-3-(3',4'5'-trimethoxybenzyl)-4-(3'',4''-methylenedioxybenzyl)-5-(1-menthyloxy)butyrolactone(140138-39-2)

Safety Data

• Hazardous Substances Data: 140138-39-2(Hazardous Substances Data)

Upstream product

• 21852-50-6 3,4,5-trimethoxybenzyl bromide 
• 112968-75-9 (5R)-(L-menthyloxy)-2(5H)-furanone 
• 6302-93-8 5-[Bis(phenylsulfanyl)methyl]-1,3-benzodioxole 
• 140138-37-0 (-)-(3S,4R,5R)-3-(3',4',5'-trimethoxybenzyl)-4-<3'',4''-methylenedioxy-α,α-bis(phenylthio)benzyl>-5-(1-menthyloxy)butyrolactone 
• 140138-37-0 (3R,4R,5R)-4-(Benzo[1,3]dioxol-5-yl-bis-phenylsulfanyl-methyl)-5-(2-isopropyl-5-methyl-cyclohexyloxy)-3-(3,4,5-trimethoxy-benzyl)-dihydro-furan-2-one 

Downstream Products

• 73149-51-6 (-)-Dihydroclusin 
• 40456-50-6 yatein 

Relevant articles and documents

Asymmetric Synthesis of Lignans of the Dibenzylbutanediol and Tetrahydrodibenzocyclooctene Series

Enolate anions obtained by conjugate addition to (-)-5-(1-menthyloxy)furan-2(5H)-one are quenched with benzyl bromides or iodides to yield homochiral dibenzylbutyrolactones.Desufurisation followed by lithium aluminium hydride reduction affords homochiral

Asymmetric Syntheses of Lignans of the Dibenzylbutyrolactone, Dibenzylbutanediol, Aryltetralin and Dibenzocyclooctadiene Series

General procedures are outlined for the asymmetric syntheses of ligands of the dibenzylbutyrolactone, dibenzylbutanediol, aryltetralin and dibenzocyclooctadiene series, from tandem addition products derived from 4-mentyloxybutenolide.