1401421-84-8Relevant academic research and scientific papers
Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety
Higuchi, Masakazu,Nakamura, Kohei,Horike, Satoshi,Hijikata, Yuh,Yanai, Nobuhiro,Fukushima, Tomohiro,Kim, Jungeun,Kato, Kenichi,Takata, Masaki,Watanabe, Daisuke,Oshima, Shinji,Kitagawa, Susumu
, p. 8369 - 8372 (2012)
Charged up: A novel porous coordination polymer with a charged organic surface (COS) comprising a zwitterionic organic linker, viologen, has been synthesized. The COS shows strong Lewis acidity accompanied with flexibility, and the isosteric heat of H2 adsorption is 9.5 kJ mol-1, which is comparable to that of open metal sites (OMSs). Copyright
