1401430-51-0Relevant academic research and scientific papers
Isolation and characterization of stable iron(I) sulfide complexes
Rodriguez, Meghan M.,Stubbert, Bryan D.,Scarborough, Christopher C.,Brennessel, William W.,Bill, Eckhard,Holland, Patrick L.
, p. 8247 - 8250 (2012)
The first examples of iron(I) sulfide complexes are presented, in contrast with the +2 and +3 oxidation states that are well-known in synthetic and biological systems. Spectroscopic and computational studies show a high-spin d7 configuration at the metal. Alkali metal cations play a key role in supporting the unusually low oxidation state. Copyright
