1401606-96-9Relevant academic research and scientific papers
Syntheses, structural characteristics, and antimicrobial activities of new organotin(IV) 3-(4-bromophenyl)-2-ethylacrylates
Muhammad, Niaz,Zia-Ur-Rehman,Shujah, Shaukat,Shah, Afzal,Ali, Saqib,Meetsma, Auke,Hussain, Zahid
, p. 3766 - 3775 (2012)
New organotin(IV) carboxylates, [n-Bu2SnL2] (1), [Et2SnL 2] (2), [Me2SnL2] (3), [n-Oct 2SnL2] (4), [n-Bu3SnL]n (5), [Me3SnL]n (6), and [Ph3SnL]n (7), where L=3-(4-bromophenyl)-2-ethylacrylate, were synthesized and characterized by elemental analysis, FT-IR, and multinuclear NMR (1H, 13C, and 119Sn). Spectroscopic studies confirm coordination of L to the organotin moiety via COO group. Single-crystal X-ray analysis reveals bridging mode of coordination in 6. Packing diagram established a supramolecular cage-like structure for 6 due to Sn-O interactions (3.287 A). Subsequent antimicrobial activities proved them to be active biologically.
