1401685-99-1

Basic information

• Product Name: [Zn(2-(4-pyridyl)benzimidazole)(benzophenone-2,4'-dicarboxylate)]n
• CAS NO: 1401685-99-1
• Molecular Weight: 528.839
• Mol File: 1401685-99-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Zn(2-(4-pyridyl)benzimidazole)(benzophenone-2,4'-dicarboxylate)]n(CAS DataBase Reference)
• NIST Chemistry Reference: [Zn(2-(4-pyridyl)benzimidazole)(benzophenone-2,4'-dicarboxylate)]n(1401685-99-1)
• EPA Substance Registry System: [Zn(2-(4-pyridyl)benzimidazole)(benzophenone-2,4'-dicarboxylate)]n(1401685-99-1)

Safety Data

• Hazardous Substances Data: 1401685-99-1(Hazardous Substances Data)

Upstream product

• 2208-59-5 2-(pyridin-4-yl)-1H-benzo[d]imidazole 
• 85-58-5 2,4'-dicarboxybenzophenone 

Relevant articles and documents

Hydrothermal synthesis of five new coordination polymers based on benzophenone-2, 4'-dicarboxylic acid and N-donor spacers

Five new coordination polymers, namely, [Ni2(L)2(4, 4'-bipy)3)]·H2O]n (1), [Ni 2(L)2(O) (bpp)2]n (2), [Zn(L)(bib)0.5]n (3), [Zn(L)(PyBIm)]n (4), and [Zn3(L)2(OH)(im)]n (5) [H2L = benzophenone-2, 4'-dicarboxylic acid, 4, 4'-bipy = 4, 4'-bipyridine, bpp = 1, 3-bis(4-pyridyl)propane, PyBIm = 2-(4-pyridyl)benzimidazole, and im = imidazole] were synthesized under hydrothermal conditions. Structure determination revealed that compound 1 is a 3D network and exhibits a 4-connected metal-organic framework with (42.63.8) topology, whereas compounds 2, 3, 4, and 5 are two-dimensional layer structures. In compounds 2-4, dinuclear metal clusters are formed through carboxylic groups. In compound 5, trinuclear metal clusters are formed through μ3-OH and carboxylic groups. The carboxylic groups exhibit three coordination modes in compounds 1-5: monodentately, bidentate-chelating, and bis-monodentately. Furthermore, the luminescent properties for compounds 3, 4, and 5 were investigated. Copyright