140173-59-7Relevant articles and documents
Photocatalytic Transformations of 3,3,3,3-Tetramethyl-4,5-diphenyl-4,5-bi-3H- pyrazolyl. Synthesis and Photolysis of the First (1-Cyclopropenyl)pyrazole
Kuznetsov,Kuchuk,Tunik
, p. 245 - 249 (2007/10/03)
The main product of exhaustive photolysis of 3,3,3′,3′-tetramethyl-4′,5-diphenyl-4,5′-bi-3H-pyrazolyl in the presence of Rh6(CO)16 is 2,7-dimethyl-3,6-diphenylocta-2,6-dien-4-yne. At shorter irradiation and with less catalyst the int
REACTION OF 2-DIAZOPROPANE WITH DIPHENYLBIACETYLENE AND PHOTOLYSIS OF THE OBTAINED 3H-PYRAZOLES. SYNTHESIS OF 3,3-DIMETHYL-1-PHENYL-2-PHENYLETHYNYLCYCLOPROPENE - THE FIRST CONJUGATED ALKYNYLCYCLOPROPENE
Kuznetsov, M. A.,Dorofeeva, Yu. V.,Semenovskii, V. V.,Gindin, V. A.,Studienikov, A. N.
, p. 2122 - 2134 (2007/10/02)
The addition of 2-diazopropane to diphenylbiacetylene takes place slowly.Even with a large excess of the diazo compound it leads to a mixture in which the main components are initial biacetylene, two regioisomeric phenylethynyl-3H-pyrazoles, and the produ