140174-63-6Relevant academic research and scientific papers
Stereoselective template-directed C-glycosidation. Silver(I)-mediated intramolecular reactions of (2-pyridylthio)glycosidic silyl enol ethers
Craig,Munasinghe
, p. 663 - 666 (2007/10/02)
The synthesis and highly stereoselective intramolecular cyclization reactions of a series of (2-pyridylthio)glycosides possessing silyl enol ether-containing appended groups are described. The cyclizations are explained in terms of S(N)1-like reactions proceeding via anomeric cationic species.
