14019-39-7Relevant academic research and scientific papers
Scrambling of P-SP and P-SC Bonds between Tetraphosphorus Decasulphide and Phosphorotetrathioic Esters
Demarcq, Michel C.
, p. 2221 - 2224 (2007/10/02)
The thermal redistribution of P4S10 with (RS)3PS (R=alkyl or aryl) generates metaphosphorotrithioic esters (RSPS2)2 and relatively smaller amounts of symmetrical 2S as 'middle' and 'end' species respectively.Reacting P4S10 with thiols affords similar mixtures.With dithiols HS(CH2)nSH (n=2 or 3), no 'middle' compound was obtained but only 'end' and 'ortho' derivatives, chiefly 2Y (A=alkylene, Y=-S- or -SAS- respectively).
