1401905-05-2

Basic information

• Product Name: C₂₃H₃₀OSi
• Synonyms: C₂₃H₃₀OSi
• CAS NO: 1401905-05-2
• Molecular Weight: 350.576
• Mol File: 1401905-05-2.mol

Chemical Properties

• CAS DataBase Reference: C₂₃H₃₀OSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₃H₃₀OSi(1401905-05-2)
• EPA Substance Registry System: C₂₃H₃₀OSi(1401905-05-2)

Safety Data

• Hazardous Substances Data: 1401905-05-2(Hazardous Substances Data)

Upstream product

• 110-62-3 pentanal 
• 51703-66-3 (S)-(-)-1-heptyn-3-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 54340-72-6 ethyl (E)-2-heptenoate 
• 33467-76-4 (E)-hept-2-en-1-ol 
• 104528-17-8 (2R,3R)-(3-butyloxiranyl)methyl alcohol 

Downstream Products

• 1329675-11-7 (4S)-4-{[(tert-butyl)diphenylsilyl]oxy}oct-2-ynal 
• 1401904-89-9 (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane 

Relevant articles and documents

Total synthesis of umuravumbolide

A simple and efficient stereoselective total synthesis of (+)-umuravumbolide (1b) and (-)-deacetylumuravumbolide (1a) starting from commercially available pentanal is described. The synthesis involves Sharpless asymmetric epoxidation, Jacobsen's hydrolytic kinetic resolution (HKR), and the Yamaguchi oxirane opening as key steps (Scheme2).