140199-80-0Relevant articles and documents
Bis(ylide)-substituted phosphenium and phosphonium halides
Schmidpeter, Alfred,Jochem, Georg,Klinger, Christian,Robl, Christian,Noeth, Heinrich
, p. 87 - 102 (1997)
The bis(triphenylphosphoniumylidyl)halophosphines expected from the condensation of ylidyl dihalophosphines with trimethylsilyl ylides or of their addition to carbodiphosphoranes enter a spontaneous dissociation to yield bis(ylidyl)phosphenium halides.The
Spontaneous dissociation of phosphoniumylidyl-chlorophosphines to ionic phosphenium chlorides
Schmidpeter, Alfred,Jochem, Georg
, p. 471 - 474 (2007/10/02)
The products from the replacement of two chlorofunctions of PCl3 by a pair of phosphoniumylidyl substituents or by both a phosphoniumylidyl and an amino substituent are ionic phosphenium chlorides and not covalent chlorophosphines.